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Structural, ferroelectric and magnetic properties of Bi0.85Sm0.15FeO3 perovskite

✍ Scribed by V. A. Khomchenko; J. A. Paixão; B. F. O. Costa; D. V. Karpinsky; A. L. Kholkin; I. O. Troyanchuk; V. V. Shvartsman; P. Borisov; W. Kleemann


Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
265 KB
Volume
46
Category
Article
ISSN
0232-1300

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✦ Synopsis


Room temperature crystal structure, ferroelectric and magnetic properties of polycrystalline Bi 0.85 Sm 0.15 FeO 3 samples were investigated. X-ray diffraction study shows that the compound possesses a dominant PbZrO 3like orthorhombic structure with √2a×2√2a×2a superlattice (a is the parameter of the cubic perovskite subcell). In contrast to piezoresponse force microscopy data demonstrating some features characteristic of ferroelectrics, polarization vs. electric field measurements reveal the behavior expected for nonpolar materials. Investigation of magnetic properties confirms that 15% samarium substitution suppresses the spin modulation typical of BiFeO 3 and induces the appearance of spontaneous magnetization.


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