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Structural features and reactions of a geminal frustrated phosphane/borane Lewis pair

✍ Scribed by Rosorius, Christoph; Daniliuc, Constantin G.; Fröhlich, Roland; Kehr, Gerald; Erker, Gerhard

Book ID
123086867
Publisher
Elsevier Science
Year
2013
Tongue
English
Weight
961 KB
Volume
744
Category
Article
ISSN
0022-328X

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✍ George R. Whittell; Edward I. Balmond; Alasdair P. M. Robertson; Sanjib K. Patra 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 309 KB

The ability of trialkyl Group 14 triflates in combination with amine and pyridine bases to dehydrogenate amine-and phosphane-borane adducts has been investigated. By using multinuclear NMR spectroscopy, it has been shown that Me 2 NH•BH 3 ( ) is efficiently converted to [Me 2 N-BH 2 ] 2 ( ) by the s