Structural Elucidation of Diastereoisomeric 1,3,6-Trioxacyclooctane Systems by Simultaneous Relaxation and Double Resonance Experiments

Solution structure of [(triphos*)RhH2(Au

Solution structure of [(triphos*)RhH2(AuPPh3)3][PF6]2 deduced by one- and two-dimensional 1H{31P} and 1H{103Rh} double-resonance techniques

✍ Daniel Imhof; Heinz Rüegger; Luigi M. Venanzi; Thomas R. Ward 📂 Article 📅 1991 🏛 John Wiley and Sons 🌐 English ⚖ 575 KB

## Abstract The application of ^1^H{^31^P} and ^1^H{^103^Rh} double‐resonance techniques for the elucidation of the solution structure of the metalla‐tetrahedrane clusters of the [(triphos\*)RhH~2~(AuPPh~3~)~3~][PF~6~]~2~ type, with the chiral tripodal phosphine triphos\* [__RRR/SSS__‐ or __RRS/SSR