Structural effects on the iodine cation basicity of organic bases in the gas phase
โ Scribed by Abboud, Jose Luis M.; Notario, Rafael; Santos, Lucia; Lopez-Mardomingo, Carmen
- Book ID
- 126167082
- Publisher
- American Chemical Society
- Year
- 1989
- Tongue
- English
- Weight
- 283 KB
- Volume
- 111
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
## Abstract The effects of the oxidation state, the ligand, and the solvent on structures and energetics of cationic iron complexes are investigated by means of electrosprayโionization mass spectrometry. Insights into the potentialโenergy surfaces of FeX^+^, FeX~2~^+^, and XFe(OCH~3~)^+^ ions (X =
The change in the proton affinity (PA) and basicity (GB) of pyridine with substituents have been considered by quantum mechanical methods at the B3LYP/6-311++G(d,p) level of theory. The PA and GB values increase by the electron-donating substituents and decrease by the electron-withdrawing substitue