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Structural effects on photophysical processes in saturated amines

✍ Scribed by Artur M. Halpern; Robert M. Danziger

Publisher: Elsevier Science
Year: 1972
Tongue: English
Weight: 483 KB
Volume: 16
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(72)80461-5

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## Abstract The ^17^O NMR chemical shifts of 14 __N__‐methylpiperidine‐__N__‐oxides and five __N__‐methyltetradecahydroacridine‐__N__‐oxides were measured. The effects of steric factors, such as γ‐__gauche__ and 1,3‐__syn__‐axial interactions of the N^+^—O^−^ oxygen, on the ^17^O chemical shifts ar