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Structural effects in solvolytic reactions. 38. Carbon-13 NMR studies of carbocations. 6. Effect of increasing electron demand on the chemical shifts of the .alpha.-carbon atoms in substituted aryldialkyl carbocations. Correlation of the data with a new set of substituent constants, .sigma..alpha.-C+

✍ Scribed by Brown, Herbert C.; Kelly, David P.; Periasamy, Mariappan

Book ID: 127152052
Publisher: American Chemical Society
Year: 1981
Tongue: English
Weight: 540 KB
Volume: 46
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo00329a003

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📜 SIMILAR VOLUMES

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[Part 1: Physical Sciences] || Structural Effects in Solvolytic Reactions; Carbon-13 NMR Studies of Carbocations: Effect of Increasing Electron Demand on the Carbon-13 NMR Shifts in Substituted tert-cumyl and 1-aryl-1-cyclopentyl Carbocations--Correlation or the Data by a New Set of Substituent Constants, σC+

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Structural effects in solvolytic reactions. 44. Effect of increasing electron demand on the carbon-13 NMR shifts in 1-aryl-1-hydroxyethyl carbocations. Deviations in the .sigma.C+-.DELTA..delta.C+ plot for these protonated acetophenones containing strongly electron-withdrawing substituents

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Structural effects in solvolytic reactions. 37. Effect of increasing electron demand on carbon-13 NMR shifts in the 9-aryl-exo-5,6-trimethylene- and 9-aryl-endo-5,6-trimethylene-9-norbornyl carbocations. Effect of the cationic carbon center on remote carbon atoms in the skeleton as revealed by increasing electron demand

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