Three new Cu II /3-sb/2,2 0 -bipy complexes, [Cu(2,2 0 -bipy) 2 (3-sb)]AE4 H 2 O (1), {[Cu(2,2 0 -bipy)(3-sb)(H 2 O) 2 ]AE2. 5H 2 O} n (2), and have been synthesized by hydrothermal reactions or the combination of hydrothermal reactions and solution evaporation. The molecular structure of complex 1
Structural diversity and fluorescent properties of copper(II) complexes constructed by 5-sulfosalicylate and 2,2′-bipyridine
✍ Scribed by Sai-Rong Fan; Long-Guan Zhu
- Publisher
- Elsevier Science
- Year
- 2007
- Tongue
- English
- Weight
- 272 KB
- Volume
- 827
- Category
- Article
- ISSN
- 0022-2860
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The optical absorption and luminescence spectra, the electrochemical behavior, and the X-ray crystal structure of a series of three heteroleptic Ru(II) complexes in comparison to [Ru(bipy) 3 ] 2 + are reported. The complexes examined are of the type [Ru(bipy) 2 (bipy%)](PF 6 ) 2 with bipy =2,2%-bipy
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