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Structural determination by NMR spectroscopy and molecular mechanics of the regio and diastereoisomers obtained in the addition of 2-phenylcyclohexanone to chalcone

✍ Scribed by A. de la Hoz; E. Díez-Barra; F. Langa; S. Merino; A. Rodríguez; P. Sánchez-Verdú

Publisher: Elsevier Science
Year: 1997
Tongue: French
Weight: 798 KB
Volume: 53
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(97)00736-9

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✦ Synopsis

The structure and stereochemistry of the six regio and stereoisomers obtained in the reaction of 2-Phenylcyclohexanone 1 with chalcone 2 by solvent-free phase transfer catalysis has been determined by a combination of NMR techniques and molecular mechanics calculations. The validity of the method has been confirmed by the X-ray structure determination of isomer 7.

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