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Structural control of the redox potentials and of the physiological activity by oligomerization of ferredoxin

✍ Scribed by J.J.G. Moura; A.V. Xavier; E.C. Hatchikian; J. Le Gall


Book ID
115908718
Publisher
Elsevier Science
Year
1978
Tongue
English
Weight
240 KB
Volume
89
Category
Article
ISSN
0014-5793

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## Abstract The coordination polymer {[Ni(C~20~H~32~N~8~)]~2~[TCM]}Β·5DMFΒ·8H~2~O (1) has been assembled from a Ni^II^ macrocyclic complex that contains two pyridyl pendant arms, [Ni(C~20~H~32~N~8~)](ClO~4~)~2~, and sodium tetrakis[4‐(carboxyphenyl)oxamethyl]methane (Na~4~TCM) in DMF/water. The X‐ray