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Structural Control in ATRP Synthesis of Star Polymers Using the Arm-First Method

✍ Scribed by Gao, Haifeng; Matyjaszewski, Krzysztof

Book ID
126037355
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
256 KB
Volume
39
Category
Article
ISSN
0024-9297

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Methacryloyl and/or Hydroxyl End-Functio
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## Abstract Star polymers with methacryloyl groups at the chain ends were synthesized by esterification of hydroxyl end‐functional star polymers. First, the linear hetero‐telechelic macroinitiator (MI) was prepared by ATRP using a functional initiator. The obtained MI was chain‐extended and cross‐l

Synthesis of 3-Arm Star Block Copolymers
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## Abstract Three‐arm star block copolymers were successfully synthesized by combination of “core‐first” and “coupling‐onto” strategies. First, polystyrene 3‐arm star polymers (PS‐Br)~3~ with high bromine chain‐end functionality were synthesized by atom transfer radical polymerization (ATRP) using