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Structural Considerations and Polarization Energy of Some PbFCl-Type Compounds

✍ Scribed by M. Sieskind; J. Morel


Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
262 KB
Volume
144
Category
Article
ISSN
0022-4596

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✦ Synopsis


Some ionic compounds MXY of the matlockite family (PbFCl) are characterized by the symmetry of the anions X and Y surroundings. If the cage around the ions X and Y are regular, the crystal is said to be 99regular:: and these conditions of symmetry give four equations adequate to compute the lattice parameters. Moreover, the symmetries play a decisive part on some physical properties because they are at the origin of electronic distorsions that produce dipolar moments. More precisely, it should be mentioned that X has no dipolar moment because the 5eld acting on X is zero and that only the cation M and the anion Y may have dipolar moments. Both the interactions of the induced moments as well as the polarization energy contribute to stabilize the lattice. Relations between local symmetries and polarization energy and its variation with pressure will be investigated. In the case of PbFI, with an increase in pressure the ion I moves in the cell which becomes more regular. At the same time, opposite variations of the 5elds and of the induced moments on the ions I and Pb occur so that the polarization energy decreases. This e4ect is only observable with the highly polarizable ion I and is negligible for Cl.


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