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Structural chemistry of organotin carboxylates: X. Synthesis and characterization of [{R2Sn(O2CtBu)]2O}2 (R = Me, Et, nPr and nBu). X-ray crystal structures of {[R2Sn(O2CtBu)]2O}2 (R = Me, Et)

✍ Scribed by Charu Vatsa; Vimal K. Jain; T. Kesavadas; Edward R.T. Tiekink


Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
680 KB
Volume
408
Category
Article
ISSN
0022-328X

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Reaction of cupferron [NH 4 L, L = PhN(O)NO -] with tin(IV), complex 2. The tin centers are heptacoordinated in a pentagonal bipyramidal geometry in the dimeric complex 3. diphenyltin(IV) and dimethyltin(IV) halides yields the cupferronato complexes SnL 4 (1), Ph 2 SnL 2 (2) and These complexes inco