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Structural chemistry of new ion-exchangeable tantalates with layered perovskite structure: new dion–jacobson phase MCa2Ta3O10 (M = alkali metal) and ruddlesden–popper phase Na2Ca2Ta3O10

✍ Scribed by Kenji Toda; Takashi Teranishi; Zuo-Guang Ye; Mineo Sato; Yukio Hinatsu


Book ID
114067217
Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
323 KB
Volume
34
Category
Article
ISSN
0025-5408

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✍ Venkataraman Thangadurai; Peter Schmid-Beurmann; Werner Weppner 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 450 KB

New members of Dion+Jacobson (D-J)-type layered perovskites of the general formula A[A 2 B 3 O 10 ] (A ‫؍‬ Rb, Cs; A ‫؍‬ Sr, Ba; B ‫؍‬ Nb, Ta) were prepared by solid-state reactions between the metal oxides, nitrates, and carbonates under speci5c conditions. The crystal structures were determined us