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Structural characterization of the pore forming protein TatAd of the twin-arginine translocase in membranes by solid-state 15N-NMR

✍ Scribed by Sonja D. Müller; Anna A. De Angelis; Torsten H. Walther; Stephan L. Grage; Christian Lange; Stanley J. Opella; Anne S. Ulrich


Book ID
116274541
Publisher
Elsevier Science
Year
2007
Tongue
English
Weight
503 KB
Volume
1768
Category
Article
ISSN
0005-2736

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Using dynamic 15N CPMAS NMR spectroscopy a novel double proton transfer was detected in the cyclic hydrogen bonded dimers of polycrystalline tSN,ZSN'-di-(4-bromophenyl)-formamidine. Rate constants of this process, which is degenerate within the margin of error, were obtained by lineshape (kl2 = 10 6