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Structural characterization of the pectic polysaccharide, rhamnogalacturonan-II

✍ Scribed by Andrew J. Whitcombe; Malcolm A. O'Neill; Wolfram Steffan; Peter Albersheim; Alan G. Darvill


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
817 KB
Volume
271
Category
Article
ISSN
0008-6215

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✦ Synopsis


An octasaccharide was released from sycamore cell wall rhamnogalacturonan-II (RG-II) by selective acid hydrolysis of the glycosidic linkages of apiosyl residues and purified to homogeneity by gel-permeation and high-performance anion-exchange chromatographies. The octasaccharide l contains a terminal nonreducing /3-e-arabinofuranosyl residue linked to position 2 of the a-L-rhamnopyranosyl residue of the aceric acid-containing heptasaccharide 2 that had been previously isolated from RG-II [M.W. Spellman et al. Carbohydr. Res., 122 (1983) 131-153].


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