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Structural Characterization of Molybdenum(V) Species in Aqueous HCl Solutions.

✍ Scribed by Farideh Jalilehvand; Vicky Mah; Bonnie O. Leung; Daniel Ross; Masood Parvez; Ricardo F. Aroca

Publisher
John Wiley and Sons
Year
2007
Weight
20 KB
Volume
38
Category
Article
ISSN
0931-7597

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A new trinuclear oxovanadium(V) complex with the anionic dmpp ligand (Hdmpp = 3-hydroxy-1,2-dimethyl-4-pyridinone), [V 3 O 6 (dmpp) 3 (H 2 O)](H 2 O) 2 , was isolated from the reaction of Hdmpp, KOH and sodium metavanadate at pH 4.5. The solid state structure of the [V 3 O 6 (H 2 O)(dmpp) 3 ](H 2 O)