## Abstract The dipeptide hypoglycin B, one of two toxins of the ackee fruit (__Blighia sapida__ Koenig), was characterized for the first time by NMR spectral data, which led to the discovery that it exists naturally as a pair of diastereomers. No distinction was observed in the ^1^H NMR signals of
Structural characterization of a procyanidin tetramer and pentamer from the apple by low-temperature NMR analysis
β Scribed by Yutaka Abe; Toshihiko Shoji; Nobuo Kawahara; Hiroyuki Kamakura; Tomomasa Kanda; Yukihiro Goda; Yoshihiro Ozeki
- Publisher
- Elsevier Science
- Year
- 2008
- Tongue
- French
- Weight
- 969 KB
- Volume
- 49
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
The structures of a procyanidin tetramer and pentamer from unripe apple (Malus pumila) were elucidated by low-temperature NMR analysis at Γ34 Β°C. These structures were [epicatechin-(4b?6)-epicatechin-(4b?8)-epicatechin-(4b?8)-epicatechin (1)] and [epicatechin-(4b?8)-epicatechin-(4b?8)-epicatechin-(4b?8)-epicatechin-(4b?8)-epicatechin (2)].
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The major glycolipid sulfate of the extreme halophile Halobacterium salinariurn was isolated and characterised mainly by mass spectrometry and NMR spectroscopy. The mass spectrum of the permethylated, desulfated and trimethylsilylated derivative showed the molecule to be a trihexosyl glycerol C20-di
## Abstract 3Ξ±βAcetylβ20(29)βlupeneβ24βoic acid (**1**) was isolated from the gum resin of __Boswellia serrata.__ Its presence evidently suggests, that the oxidosqualene triterpene pathway of __Boswellia serrata__ closely resembles the biosynthetic route already found in other plants. Complete ^1^H