Structural Characterization of 1:1 van der Waals Complexes of 9-Cyanoanthracene with Aprotic Solvents by Rotational Coherence Spectroscopy
โ Scribed by Egashira, Kazuhiro; Ohshima, Yasuhiro; Kajimoto, Okitsugu
- Book ID
- 126914158
- Publisher
- American Chemical Society
- Year
- 2001
- Tongue
- English
- Weight
- 132 KB
- Volume
- 105
- Category
- Article
- ISSN
- 1089-5639
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๐ SIMILAR VOLUMES
Van der Waals complexes of perylene with I-chlorobutane, prepared under supersonic jet conditions, exist in three distinct isomeric forms distinguishable by their spectral red-shifts of 265,238 and 184 cm-'. Following vibronic excitation at 355 cm-', two of these isomers yield similarly shaped and b
Rotational coherence spectroscopy involving polarized, time-correlated single-photon counting techniques has been used to measure the excited-state structures of hydrogen-bonded complexes between PPD and water at the 1: 1 and I : 2 levels of aggregation. Structure determinations involved comparison