Structural behavior of the ferromagnetic spinels AlxMo2S4 and GaxMo2S4, containing tetrahedral clusters of molybdenum atoms
β Scribed by J.M. Vandenberg; D. Brasen
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- English
- Weight
- 450 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0022-4596
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Bis(disulfide) bridged Nb(+4) cluster halide complexes [Nb 2 S 4 X 8 ] 4Β± (X = Cl, Br) were prepared by acid hydrolysis of [Nb 2 S 4 (NCS) 8 ] 4Β± in concentrated aqueous HCl or HBr, solution from which they can be isolated as double salts Cs 5 [Nb 2 S 4 X 8 ]X (X = Cl, 1; X = Br, 2). The crystal st