Structural Aspects of Vitreous PbO·2B2O3 Studied by Raman Scattering
✍ Scribed by W. L. KONIJNENDIJK; H. VERWEIJ
- Book ID
- 110814285
- Publisher
- John Wiley and Sons
- Year
- 1976
- Tongue
- English
- Weight
- 353 KB
- Volume
- 59
- Category
- Article
- ISSN
- 0002-7820
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Thermal and spectroscopic studies have been carried out on a number of glasses with wide ranging compositions in the pseudoternary glass system Li 2 O+PbO+B 2 O 3 in order to understand the structural role of PbO in these glasses. Infrared, Raman, and 11 B MAS-NMR results indicate that PbO behaves a
EPR absorption spectra of Cu 2 + were investigated in vitreous matrices of the system [70TeO2-25B2Os-5PbO] over a wide range of concentrations. The detected absorptions are strongly dependent on the matrix composition. Fluctuations of the ligand field were evident in the Cu 2 § environment. The conc