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Structural and thermochemical properties of the hydroxymethyl (CH[sub 2]OH) radical: A high precision ab initio study

โœ Scribed by Marenich, Aleksandr V.; Boggs, James E.


Book ID
118062471
Publisher
American Institute of Physics
Year
2003
Tongue
English
Weight
355 KB
Volume
119
Category
Article
ISSN
0021-9606

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A new partially structured photoelectron band appearing early in the F+CH,SCH, reaction has been assigned to the primary reaction product, CHpSCH2. This band, with adiabatic and vertical ionisation energies of 6.85 kO.03 and 7.16+0.03 eV, respectively, shows structure in two vibrational modes, with