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Structural and thermal analysis of silicon isothiocyanates complexes of Fe(III) and Mn(II)

✍ Scribed by A. Syngollitou-Kourakou; I. Tossidis


Book ID
105397732
Publisher
Springer Netherlands
Year
1989
Tongue
English
Weight
284 KB
Volume
35
Category
Article
ISSN
0022-5215

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Apoconalbumin binds \_Mn(II) at two sites with association constants of K1 = 7(%1) x lo4 and Kz = 0.4(?0.25) x lo4 M-l. The binding is tighter in the presence of excess bicarbonate resulting in K1 = l-8(\*0.2) X lo5 and K2 = 3(+2) X IO4 M-l. The electron paramagnetic resonance spectrum (at both 9 an