Structural and spectroscopic studies of Ni (II) creatinine complexes
β Scribed by A. Panfil; J.J. Fiol; M. Sabat
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 69 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0162-0134
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## Abstract Four new mononuclear metal complexes with a mononucleating Schiff base ligand containing two thiadiazoles units have been synthesized. The ligand and metal complexes were characterized by elemental analyses, IR, ^1^H, and ^13^C NMR, UVβvis, ESR, electrospray ionization mass spectra, and
XAS techniques for studying structural and electronic changes taking place after oxidation and reduction reactions of nickel complexes are described and applied to selected models for Factor 430, a nickel containing cofactor catalyzing an important step in the conversion of carbon dioxide to methane