## Spectroscopic Studies on a Copper(I1) Binuclear Complex Studies on multi-nuclear copper complexes have become one of the interesting fields of research of bioinorganic chemistry in recent years (HAY). The identification and characterization of relevant coordination complexes and studies of copp
Structural and spectroscopic studies of a metacyclophane and its binuclear Cu2+ complex
โ Scribed by Michiko B. Inoue; Lorena Machi; Motomichi Inoue; Quintus Fernando
- Publisher
- Elsevier Science
- Year
- 2001
- Tongue
- English
- Weight
- 125 KB
- Volume
- 317
- Category
- Article
- ISSN
- 0020-1693
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The 'H NMR spectra of [S]metacyclophane C&t, and of its 8,11-dichloro derivative & are reported. 2 Has a rigid conformation A between -50 and +150ยฐC. Conformation A is also the preferred one (85%) for l& at -47 OC, but l&,-A is in equilibrium with a second conformer l&-B, for which spectral paramete
The crystal structure of the binuclear Cu(II) complex [Cu(flu) 2 DMF] 2 (flu = deprotonated N-3-trifluromethylphenylanthranilic acid: DMF = dimethylformamide) has been solved by single crystal X-ray diffractometry. It crystallizes in the monoclinic space group P2 1 /c with Z = 2. The in-frared and e