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Structural and Spectral Studies of Two Mixed Anionic (1:1) CdII3[(TrIII/CrIII)(CN)6]2·15H2O Complexes (Tr=Co, Fe)

✍ Scribed by Donald F Mullica; Fernando H Alvarez; Jason A Kautz; Eric L Sappenfield


Publisher
Elsevier Science
Year
1998
Tongue
English
Weight
491 KB
Volume
140
Category
Article
ISSN
0022-4596

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The X-Ray Diffraction Analysis and Spect
✍ D.F. Mullica; P.A.B. Colot; J.A. Kautz; R.J. Smith; E.L. Sappenfield 📂 Article 📅 1997 🏛 Elsevier Science 🌐 English ⚖ 273 KB

Refinement of the crystallographic structure of (1 : 1) Cd II 3 [(Fe III /Co III ) (CN) 6 ] 2 • 14H 2 O (I) has been carried out by means of three-dimensional single-crystal X-ray diffractometry. This novel disordered mixed anionic complex crystallizes in the cubic space group Fm3 m (Z‫1؍‬ 1/3) with