Structural and optical properties of ZnMgO nanostructures formed by Mg in-diffused ZnO nanowires

✍ Scribed by Ching-Ju Pan; Hsu-Cheng Hsu; Hsin-Ming Cheng; Chun-Yi Wu; Wen-Feng Hsieh

• Publisher: Elsevier Science
• Year: 2007
• Tongue: English
• Weight: 343 KB
• Volume: 180
• Category: Article
• ISSN: 0022-4596
• DOI: 10.1016/j.jssc.2007.01.014

✦ Synopsis

ZnMgO nanostructures with wurtzite phase were prepared by thermal diffusion of Mg into the ZnO nanowires. As ZnO light-emitting devices have been operated by using ZnMgO layers as energy barrier layers to confine the carriers, it is essential to realize the characterization of ZnMgO particularly. In this work, the Mg content in Zn 1Àx Mg x O alloy determined by X-ray diffraction (XRD) and photoluminescence (PL) shows a good coincidence. The variation of lattice constant and the blueshift of near-band-edge emission indicate that Zn 2+ ions are successfully substituted by Mg 2+ ions in the ZnO lattice. In Raman-scattering studies, the change of E 2 (high) phonon line shape in ZnO:Mg nanostructures reveals the microscopic substitutional disorder. In addition to the host phonons of ZnO, two additional bands around 383 and 510 cm À1 are presumably attributed to the Mg-related vibrational modes.