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Structural and Mössbauer study of Sr2FeO3X (X = F, Cl, Br) and the magnetic structure of Sr2FeO3F

✍ Scribed by Hector, Andrew L.; Hutchings, John A.; Needs, Richard L.; Thomas, Michael F.; Weller, Mark T.

Book ID
111689008
Publisher
Royal Society of Chemistry
Year
2001
Tongue
English
Weight
182 KB
Volume
11
Category
Article
ISSN
0959-9428

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Ba3Te2O6X2 is obtained by reacting TeO2 in a BaX2 flux at 1000 °C under atmospheric conditions. The samples are characterized by powder and single crystal XRD. All four compounds crystallize in the cubic space group Fd3m with Z = 16. The structures consist of a rigid ∞ 3 [M3Te2O6] 2+ framework (M: S