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Structural and fluorescence studies of compounds with general formula [Ln(DMA)3(H2O)6](CF3SO3)3 (DMA ≡ N,N-dimethylacetamide, Ln ≡ La-Tb)

✍ Scribed by R.W. Becker; E.E. Castellano; G. Vicentini; L.B. Zinner


Book ID
116017114
Publisher
Elsevier Science
Year
1989
Weight
384 KB
Volume
148
Category
Article
ISSN
0022-5088

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Synthesis and structure of two lanthanid
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Two new lanthanide complexes of isonicotinic acid N-oxide (HL), namely [Ln(L) 2 (H 2 O) 4 ] n AE(NO 3 ) n AEn(H 2 O) for Ln = Sm or Tb, have been synthesized and characterized by spectroscopic and crystallographic methods. IR spectra suggest that isonicotinic acid N-oxide acts as a O,O 0 -bidentate