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Structural and electronic properties of 3,4-ethylenedioxythiophene, 3,4-ethylenedisulfanylfurane and thiophene oligomers: A theoretical investigation

✍ Scribed by Carlos Alemán; Elaine Armelin; José Ignacio Iribarren; Francisco Liesa; Manuel Laso; Jordi Casanovas


Book ID
116897414
Publisher
Elsevier Science
Year
2005
Tongue
English
Weight
227 KB
Volume
149
Category
Article
ISSN
0379-6779

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Mixed π-conjugated oligomers of thiophen
✍ Mathieu Turbiez; Pierre Frère; Philippe Blanchard; Jean Roncali * 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 155 KB

Conjugated oligomers based on various combinations of thiophene and 3,4-ethylenedioxythiophene (EDOT) moieties have been synthesised. Comparison of the optical and electrochemical properties shows that the introduction of a bis-EDOT core in the middle of the system produces a decrease of the HOMO± L