𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Structural and Dynamic Study of SnCl4 · 2 Me2O and SnCl4 · 2 Me2Se Preliminary communication

✍ Scribed by Steve J. Ruzicka; André E. Merbach


Book ID
102249607
Publisher
John Wiley and Sons
Year
1975
Tongue
German
Weight
310 KB
Volume
58
Category
Article
ISSN
0018-019X

No coin nor oath required. For personal study only.

✦ Synopsis


Abstract

The solid cis‐SnCl~4~ · 2Me~2~O and trans‐SnCl~4~ · 2Me~2~Se adducts have been synthesised and characterised by IR. and Raman spectroscopy. NMR. and vibrational spectroscopy show a fast cis‐trans equilibrium for both complexes in solution in an inert solvent.


📜 SIMILAR VOLUMES


Synthesis, solution behaviour and X-ray
✍ Richard A. Varga; Cristian Silvestru; Calin Deleanu 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 290 KB 👁 2 views

2-(Me 2 NCH 2 )C 6 H 4 ]SnCl 3 (1) was prepared via (i) salt elimination reaction between RLi and SnCl 4 (1 : 1 molar ratio), in toluene solution, and (ii) redistribution reaction between [2-(Me 2 NCH 2 )C 6 H 4 ] 4 Sn and SnCl 4 (1 : 3 molar ratio), in the absence of a solvent. Recrystallization fr

Tetrahydrothiophene-1-oxide, TMSO, compl
✍ Howie, R. Alan; Harrison, William T. A.; de Lima, Geraldo M.; Wardell, James L.; 📂 Article 📅 2010 🏛 Oldenbourg Wissenschaftsverlag 🌐 English ⚖ 963 KB

Crystal structures of five tin(IV) complexes containing the tetrahydrothiophene-1-oxide ligand, C 4 H 8 SO, TMSO, with Sn--O interactions, are described. They are trigonal bipyramidal Ph 2 SnCl 2 (TMSO), with TMSO and Cl in axial sites, and the octahedral complexes, Ph 2 SnCl 2 (TMSO) 2 and SnX 4 (T