2-(Me 2 NCH 2 )C 6 H 4 ]SnCl 3 (1) was prepared via (i) salt elimination reaction between RLi and SnCl 4 (1 : 1 molar ratio), in toluene solution, and (ii) redistribution reaction between [2-(Me 2 NCH 2 )C 6 H 4 ] 4 Sn and SnCl 4 (1 : 3 molar ratio), in the absence of a solvent. Recrystallization fr
✦ LIBER ✦
Structural and Dynamic Study of SnCl4 · 2 Me2O and SnCl4 · 2 Me2Se Preliminary communication
✍ Scribed by Steve J. Ruzicka; André E. Merbach
- Book ID
- 102249607
- Publisher
- John Wiley and Sons
- Year
- 1975
- Tongue
- German
- Weight
- 310 KB
- Volume
- 58
- Category
- Article
- ISSN
- 0018-019X
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
The solid cis‐SnCl~4~ · 2Me~2~O and trans‐SnCl~4~ · 2Me~2~Se adducts have been synthesised and characterised by IR. and Raman spectroscopy. NMR. and vibrational spectroscopy show a fast cis‐trans equilibrium for both complexes in solution in an inert solvent.
📜 SIMILAR VOLUMES
Synthesis, solution behaviour and X-ray
✍
Richard A. Varga; Cristian Silvestru; Calin Deleanu
📂
Article
📅
2005
🏛
John Wiley and Sons
🌐
English
⚖ 290 KB
👁 2 views
Synthesis and crystal structure of Me2Sn
✍
T.K. Chattopadhyay; A.K. Kumar; A. Roy; A.S. Batsanov; E.B. Shamuratov; Yu.T. St
📂
Article
📅
1991
🏛
Elsevier Science
🌐
English
⚖ 330 KB
Organotin-DMIT complexes: crystal struct
✍
Solange M.S.V. Doidge-Harrison; R. Alan Howie; John T.S. Irvine; Gavin Spencer;
📂
Article
📅
1991
🏛
Elsevier Science
🌐
English
⚖ 243 KB
Synthesis and structure of diethyltindic
✍
Jörg Lorberth; Sigrid Wocadlo; Werner Massa; Natalia S. Yashina; Evgenii V. Grig
📂
Article
📅
1994
🏛
Elsevier Science
🌐
English
⚖ 327 KB
Synthesis and molecular structures of th
✍
Yu. V. Torubaev; A. A. Pasynskii; A. R. Galustyan; P. Mathur
📂
Article
📅
2009
🏛
SP MAIK Nauka/Interperiodica
🌐
English
⚖ 218 KB
Tetrahydrothiophene-1-oxide, TMSO, compl
✍
Howie, R. Alan; Harrison, William T. A.; de Lima, Geraldo M.; Wardell, James L.;
📂
Article
📅
2010
🏛
Oldenbourg Wissenschaftsverlag
🌐
English
⚖ 963 KB
Crystal structures of five tin(IV) complexes containing the tetrahydrothiophene-1-oxide ligand, C 4 H 8 SO, TMSO, with Sn--O interactions, are described. They are trigonal bipyramidal Ph 2 SnCl 2 (TMSO), with TMSO and Cl in axial sites, and the octahedral complexes, Ph 2 SnCl 2 (TMSO) 2 and SnX 4 (T