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Structural Analysis of Metal Interactions with the Dinucleotide Duplex, dCG·dCG, Using Ion Mobility Mass Spectrometry

✍ Scribed by Baker, Erin Shammel; Manard, Manuel J.; Gidden, Jennifer; Bowers, Michael T.


Book ID
126874000
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
89 KB
Volume
109
Category
Article
ISSN
0022-3654

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The fast atom bombardment (FAB)mass spectra of a series of dinucleotide analogs, compounds 1-8 with alkaline earth metal chlorides (CaCI,, MgCI,, SrCI, and BaCI,) were studied in a thioglycerol matrix. The positive-ion FAB mass spectra of 1-8 with CaCI, gave [ M + Ca -HI +, [ M + CaClj + and [ M + C