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Structural analysis of complex oxides Ln2MnTa1+xO7+δ (Ln = rare earth and yttrium) with pyrochlore-related structures

✍ Scribed by G Chen; H Takenoshita; H Satoh; N Kamegashira; M Miyamoto

Book ID
116597478
Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
197 KB
Volume
374
Category
Article
ISSN
0925-8388

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✍ Pierre Strobel; Siwar Zouari; Rafik Ballou; Abdelwaheb Cheikh-Rouhou; Jean-Claud 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 962 KB

A number of new quaternary rare-earth pyrochlores Ln 2 BSbO 7 are reported with Ln ¼ Pr, Nd, Eu, Gd or Dy, B ¼ Sc, Ga or In. These compositions extend the range of available rare-earth pyrochlores with diamagnetic B-site cations, especially for early lanthanides (Pr, Nd). Rietveld refinements and Mo