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Structural Analyses of N-Acetylated 4-(Dimethylamino)pyridine (DMAP) Salts

✍ Scribed by Volker Lutz; Jörg Glatthaar; Christian Würtele; Michael Serafin; Heike Hausmann; Peter R. Schreiner


Book ID
102794439
Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
637 KB
Volume
15
Category
Article
ISSN
0947-6539

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In(C 6 F 5 ) 3 ´CH 3 CN and In(C 6 F 5 ) 3 ´glyme were synthesized from InCl 3 and Cd(C 6 F 5 ) 2 in CH 3 CN or glyme in 43% and 35% yield, respectively. Replacement of CH 3 CN or (C 2 H 5 ) 2 O by DMAP yielded the corresponding 1 : 1-adduct. [PNP][In(C 6 F 5 ) 4 ] was best prepared from the corres