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Structural analogies between homogeneous and heterogeneous catalysts for the stereospecific polymerization of 1-alkenes

✍ Scribed by Paolo Corradini; Vincenzo Busico; Luigi Cavallo; Gaetano Guerra; Michele Vacatello; Vincenzo Venditto


Publisher
Elsevier Science
Year
1992
Weight
672 KB
Volume
74
Category
Article
ISSN
0304-5102

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✍ Yuan Kong; Jianjun Yi; Xiuli Dou; Weijiao Liu; Qigu Huang; Kejing Gao; Wantai Ya 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 476 KB

Comparison with the conventional ZieglereNatta catalyst TiCl 4 /MgCl 2 (I), the modified supported Zie-glereNatta catalysts (iso-PentylO)TiCl 3 /MgCl 2 (II) and (BzO)TiCl 3 /MgCl 2 (III) were prepared as efficient catalysts for copolymerization of ethylene with 1-octene. The complexes (II) and (III)