Strongly luminescing ruthenium(II)/ruthenium(II) and ruthenium(II)/platinum(II) binuclear complexes
β Scribed by Sahai, Ram; Baucom, David A.; Rillema, D. Paul
- Book ID
- 121279859
- Publisher
- American Chemical Society
- Year
- 1986
- Tongue
- English
- Weight
- 404 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0020-1669
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π SIMILAR VOLUMES
The complex Ru(i-biq)y, where i-blq IS 2.2'-bls-lsoqumolme, was synrheslzcd and srudxd spec~roscoprully rmd elrctrochemically. The strong luminescence exhibited at 77 R m rigd glasses 15 characterized as a trIplet h~ndsenrcrcd cmssion. It us the first example of hgnd-centered luminescence from a Ru(
2. 227 mg of cysteamine and 392 mg of Mohr's salt are dissolved in 50 ml of 1 M tris-HC1 buffer (pH = 7.0). The p H is then adjusted to 9.5 by 1 N NaOH, and a solution of 504 mg of the sodium salt of riboflavin monophosphate (FMN) in 25 ml of H 2 0 is added. After 5 minutes the mixture is transferre