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Strong Ferromagnetic Interactions in [V8O14(H−2taci)2]: An Unprecedented Large Spin Ground State for a Vanadyl Cluster

✍ Scribed by Kaspar Hegetschweiler; Bernd Morgenstern; Jon Zubieta; Pamela J. Hagrman; Nicola Lima; Roberta Sessoli; Federico Totti


Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
145 KB
Volume
43
Category
Article
ISSN
0044-8249

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Strong Ferromagnetic Interactions in [V8
✍ Kaspar Hegetschweiler; Bernd Morgenstern; Jon Zubieta; Pamela J. Hagrman; Nicola 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 144 KB

The control of the spin of the ground state in molecular clusters behaving like single molecule magnets (SMM) has been an important challenge in coordination chemistry. The spin value is a critical parameter because the barrier for the orientation of the magnetization depends on the square of it. [1