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Strong Closed-Shell Interactions in Inorganic Chemistry

✍ Scribed by Pyykkö, Pekka


Book ID
111688181
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
993 KB
Volume
97
Category
Article
ISSN
0009-2665

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Extremely Strong s2 – s2 Closed-Shell In
✍ Ralf Wesendrup; Peter Schwerdtfeger 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 98 KB

Closed-shell interactions (CSI) range from extremely weak van der Waals forces, as for the helium dimer (dissociation energy, E d 9.06 Â 10 À2 kJ mol À1 ), [1, to strong aurophilic interactions (E d up to 30 kJ mol À1 ) [3] . The strength of the latter lie almost in the order of covalent bonds, and