Two theoretical models for the interpretation of the existing data of CH-stretching overtones' vibrational circular dichroism data are presented. The first model is based on the quantum mechanical Van Vleck contact transformation theory and is applied to the full vibrational problem, the second is b
Stretching vibrational overtone and combination states in silicon tetrafluoride
β Scribed by Lauri Halonen
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- English
- Weight
- 607 KB
- Volume
- 120
- Category
- Article
- ISSN
- 0022-2852
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π SIMILAR VOLUMES
High-resolution IR spectra of ethylene cooled in a molecular jet have been investigated revealing perturbations of some rovibrational lines of n 9 and n 11 fundamentals due to resonant Coriolis interactions. In the range of J up to 4, two combination states, n 3 / n 8 / n 10 and n 6 / n 8 / n 10 , w
The vibrational energy relaxation (VER) of polyatomic molecules has been the central issue in many of the chemical reactions in condensed phase [1][2][3][4][5][6][7][8][9][10][11][12][13][14][15][16][17] as well as in gas phase . The vibrational energy introduced to the molecule is immediately redis