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Stress softening in natural rubber vulcanizates. Part III. Carbon black-filled vulcanizates

โœ Scribed by J. A. C. Harwood; A. R. Payne

Publisher
John Wiley and Sons
Year
1966
Tongue
English
Weight
463 KB
Volume
10
Category
Article
ISSN
0021-8995

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Stress softening in natural rubber vulca
Stress softening in natural rubber vulcanizates. Part IV. Unfilled vulcanizates
โœ J. A. C. Harwood; A. R. Payne ๐Ÿ“‚ Article ๐Ÿ“… 1966 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 358 KB

Stress softening (Mullins effect) is observed in gum natural rubber vulcanizates. The magnitude of this softening is similar to that in carbon black-filled vulcanizates. The amount of stress softening is slightly greater in vulcanizates cured to produce predominantly polysulfide crosslinks than in t

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Considerable stress softening (Mullins effect) occurs in both gum and filler loaded vulcanizates of natural rubber and SBR. When compared at the same stress, the extent of softening is similar in bdth gum and filled vulcaniates. The stress softening is shown to be mainly due to changes in the rubber

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โœ A. R. Payne ๐Ÿ“‚ Article ๐Ÿ“… 1962 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 417 KB ๐Ÿ‘ 2 views

## Abstract The dynamic shear modulus at very high strains, (__G__~โˆž~), of carbon black filler loaded vulcanizates is regarded as due to the product of two factors: (__a__) a hydrodynamic interaction due to filler particles, and (__b__) a second factor for which evidence is given suggesting that it