Strong thermal relaxation effects of low energy excitations have been studied in polymethyl methacrylate (PMMA) at low temperatures. These excitations are characteristic of the amorphous structure and their relaxation gives rise to large apparent heat leaks after temperature changes in low temperatu
Stress relaxation in polymethyl methacrylate in liquid media
โ Scribed by A. N. Tynnyi; V. M. Gural; N. G. Kalinin; A. I. Soshko
- Publisher
- Springer
- Year
- 1972
- Tongue
- English
- Weight
- 276 KB
- Volume
- 5
- Category
- Article
- ISSN
- 1573-885X
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The sequence length and tacticity of methyl methacrylate polymers prepared at 303-363ยฐK in the presence of trichlorobromomethane as a transfer agent were measured from NMR spectra. The lengths did not change appreciably but there was an increase in syndiotacticity with increasing concentration of tr