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Stress and thermally induced crystallization in crosslinked cis-polybutadiene

✍ Scribed by F. De Candia; G. Romano; R. Russo

Publisher
John Wiley and Sons
Year
1987
Tongue
English
Weight
586 KB
Volume
34
Category
Article
ISSN
0021-8995

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✦ Synopsis

Strain and thermally induced crystallization was investigated in crosslinked 1,4-cis-polybutadiene. Data obtained at room temperature, where the crystallization can be only strain induced, &ow that at any given deformation the elastic modulus is a simple function of the crystalline content. On this basis, the modulus data were used to analyze the crystallization phenomena under stress at low temperature. Results show that crystallization occurs with a two-stage mechanism that depends on deformation and temperature.

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