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Strength of the Benzene−Water Hydrogen Bond

✍ Scribed by Feller, David

Book ID
120238210
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
54 KB
Volume
103
Category
Article
ISSN
1089-5639

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There are large differences between the acidity of the enol of the acyclic diketone, 2,4-pentanedione and those of two cyclic diketones, 1,3-cyclopentanedione and 1,3-cyclohexanedione. Computational studies have demonstrated that these differences are largely due to the strength of the internal low-