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Strained Small Ring Compounds: Bridgehead Substituted Bicyclo [2.1.1]hexanes

✍ Scribed by Wiberg, Kenneth B.; Lowry, Betty R.

Book ID
120001286
Publisher
American Chemical Society
Year
1963
Tongue
English
Weight
932 KB
Volume
85
Category
Article
ISSN
0002-7863

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✍ Gavin T. Binmore; John C. Walton; William Adcock; Christopher I. Clark; Alexande πŸ“‚ Article πŸ“… 1995 πŸ› John Wiley and Sons 🌐 English βš– 623 KB

## Abstract 4‐Substituted bicyclo [2.2.2] oct‐1‐yl radicals were generated by bromine atom abstraction from the corresponding 1‐bromobicyclo [2.2.2] octanes and observed in solution by EPR spectroscopy. A tendency towards lower __a__(H~Ξ²~) and __a__(H~Ξ³~) values for inductively electron‐withdrawing