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Strained Hydrocarbons from Cyclic Diynes: Preparation and Reactivity

✍ Scribed by Sabine Bethke; Stefan Brand; Bjorn Treptow; Rolf Gleiter


Publisher
John Wiley and Sons
Year
2003
Weight
51 KB
Volume
34
Category
Article
ISSN
0931-7597

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The kinetics and the products of the bromination of several cyclic allenes, from C 9 to C 13 (1 a Β± e), with tetrabutylammonium tribromide (TBAT) and Br 2 have been investigated in 1,2-dichloroethane (DCE) and methanol. The first product of the interaction between the allene and Br 2 is a 1:1 p comp