✦ LIBER ✦

Strain energies of some bridgehead olefins as calculated with the MM2 force field

✍ Scribed by Philip M. Warner; Stephen Peacock

Publisher: John Wiley and Sons
Year: 1982
Tongue: English
Weight: 264 KB
Volume: 3
Category: Article
ISSN: 0192-8651
DOI: 10.1002/jcc.540030317

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✦ Synopsis

Abstract

The MM2 force field has been used to calculate the strain energies of a representative series of bridgehead alkenes, and the results compared to similar previous calculations using the MM1 force field. The new results roughly parallel the old ones, although the strain energy of a given compound is normally higher with MM2 than MM1. These differences are largely negated, however, when the OS (olefinic strain) value is considered.

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