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Strain effects on the microphase separation in interpenetrating polymer networks and cross-linked polymer mixtures

✍ Scribed by Semjon Stepanow; Harry L. Frisch


Publisher
John Wiley and Sons
Year
1995
Tongue
English
Weight
348 KB
Volume
4
Category
Article
ISSN
1022-1344

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✦ Synopsis


Abstract

We study the microphase separation in cross‐linked polymer mixtures and interpenetrating polymer networks by taking into account the coupling between the fluctuations of the order parameter and the strain tensor. We predict that thermal fluctuations of the order parameter decrease the compression and shear moduli and that compression of the sample decreases the critical temperature of microphase separation. We also compute the scattering function in the case of shear and uniaxial deformations.


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Latex interpenetrating polymer networks
✍ P. Nagarajan; C. K. Mital; M. K. Trivedi πŸ“‚ Article πŸ“… 1996 πŸ› John Wiley and Sons 🌐 English βš– 440 KB πŸ‘ 2 views

Latex interpenetrating polymer networks (LIPNs) were prepared by swelling the polyacrylate seed (comprised of methyl methacrylate and n-butyl acrylate in the ratio of 45 : 55 by weight), having different amounts of methacrylic acid (MAA) ranging from 0 to 6 w t %, with styrene monomer, whose polymer