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Stoichiometry and thermodynamic property of massively cyclohexane-solvated C60

✍ Scribed by Yatsuhisa Nagano; Tadanobu Tamura; Tetsu Kiyobayashi

Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
516 KB
Volume
228
Category
Article
ISSN
0009-2614

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✦ Synopsis

A cyclohexane-solvated Cao compound was calorimetrically found to form two stoichiometric crystalline phases, C,(C,H,,) Is.7 and C60(C6H& The former phase has a novel structure AB13 composed of binary spheres. The solubility of C60(C6HIZ)13.7 was measured at various temperatures. CsO( C6H12) 13.7 is an incongruently melting compound with a peritectic point at T= 77Β°C.

πŸ“œ SIMILAR VOLUMES

Stoichiometry and phase behavior of carb
Stoichiometry and phase behavior of carbon tetrachloride solvates of C60
✍ Yatsuhisa Nagano; Tadanobu Tamura πŸ“‚ Article πŸ“… 1996 πŸ› Elsevier Science 🌐 English βš– 344 KB

Two solvated crystals of C6o were formed from CC14 solutions. It was found that the cubic solvated crystal is composed of a C6o(CCI4)13 formula unit while the hexagonal crystal has a C6o(CC14) 2 unit. These solvates have phase behavior comparable with that of cyclohexane solvates of C6o, being close