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Stoichiometric Reduction of CO2 to CO by Aluminum-Based Frustrated Lewis Pairs

✍ Scribed by Gabriel Ménard; Prof. Dr. Douglas W. Stephan


Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
355 KB
Volume
123
Category
Article
ISSN
0044-8249

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Unique Evidence for a RhIII to RhI Reduc
✍ Michele Aresta; Angela Dibenedetto; Immacolata Tommasi 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 292 KB

Rh III carbonate generated from either a peroxocarbonate complex [RhCl(CO 4 )(PR 3 ) 3 ] or [RhCl 3 (PR 3 ) 3 ] and Na 2 CO 3 , is reduced to Rh I by deoxygenation of the carbonate moiety to CO 2 by an out-of-sphere phosphane. The reaction takes Scheme 1. Alternative pathways for CO 2 reaction with