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Stochastic theory of collisional energy transfer: quantum description of translation in a model problem

✍ Scribed by Adam J. Makowski


Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
298 KB
Volume
125
Category
Article
ISSN
0009-2614

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✦ Synopsis


Master equation transition probabilities, both quantum and semiclassical, are compared with exact quantum caiculattons for the Landau-Teller model. The quantum description of relative motion during a collision is found to be important for low relative energies.


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## Abstract Electronic excitation energy transfer (EET) is described theoretically for the chromophore complex **P**~4~ formed by a butanediamine dendrimer to which four pheophorbide‐__a__ molecules are covalently linked. To achieve a description with atomic resolution, and to account for the effec