Stochastic model for living radical polymerisation of styrene initiated by epoxide radical ring opening

Synthesis of AB2 3- and AB4 5-Miktoarm S

Synthesis of AB2 3- and AB4 5-Miktoarm Star Copolymers Initiated from Dendritic Tri- and Penta-Functional Initiators by Combination of Ring-Opening Polymerization of ε-Caprolactone and Nitroxide-Mediated Radical Polymerization of Styrene

✍ Yozo Miura; Yumi Sakai; Keisuke Yamaoka 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 186 KB

## Abstract Summary: Well‐defined AB~2~ 3‐ and AB~4~ 5‐miktoarm star copolymers were prepared by combination of ring‐opening polymerization (ROP) and nitroxide‐mediated radical polymerization (NMRP) using dendritic tri‐ and penta‐functional initiators. Initially, two kinds of dendritic initiators h